Synthesis and X-ray Crystal Structure of a Stable cis-1,2-bis(diphenylphosphino)ethene Monodentate Thiolate Platinum Complex and TGA Studies of its Precursors
The stable Pt(II) complex [Pt(SPh)2(dppen) (4), (dppen, Ph2PCH=CHPPh2) was obtained from [PtCl(SPh)2(SnPh3)cod] (1) (cod = 1,5-cyclooctadiene) by reductive elimination reaction of SnClPh3 and substitution of the cod ligand by the diphosphine, albeit in low yields. Yields of 80% were obtained when [P...
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| Outros Autores: | , , |
| Formato: | article |
| Idioma: | eng |
| Publicado em: |
2002
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| Texto completo: | http://old.scielo.br/scielo.php?script=sci_arttext&pid=S0103-50532002000100013 |
| País: | Brasil |
| Oai: | oai:scielo:S0103-50532002000100013 |