Catalytic promiscuity: catecholase-like activity and hydrolytic DNA cleavage promoted by a mixed-valence FeIII FeII complex

Catalytic promiscuity has emerged as an important property of many enzymes since the relationship of this property to enzymatic evolution became clear. Simultaneously, the development of suitable biomimetic catalytic systems capable of mimicking the promiscuous catalytic properties of such enzymes r...

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Bibliographic Details
Main Author: Neves,Ademir (author)
Other Authors: Bortoluzzi,Adailton J. (author), Jovito,Rafael (author), Peralta,Rosely A. (author), Souza,Bernardo de (author), Szpoganicz,Bruno (author), Joussef,Antônio C. (author), Terenzi,Hernán (author), Severino,Patricia C. (author), Fischer,Franciele L. (author), Schenk,Gerhard (author), Riley,Mark J. (author), Smith,Sarah J. (author), Gahan,Lawrence R. (author)
Format: article
Language:eng
Published: 2010
Subjects:
mixed-valence FeIII FeII complex
unsymmetrical ligand
catalytic promiscuity
diester and DNA cleavage
catecholase activity
Online Access:http://old.scielo.br/scielo.php?script=sci_arttext&pid=S0103-50532010000700007
Country:Brazil
Oai:oai:scielo:S0103-50532010000700007

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http://old.scielo.br/scielo.php?script=sci_arttext&pid=S0103-50532010000700007

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