Catalytic promiscuity: catecholase-like activity and hydrolytic DNA cleavage promoted by a mixed-valence FeIII FeII complex

Catalytic promiscuity has emerged as an important property of many enzymes since the relationship of this property to enzymatic evolution became clear. Simultaneously, the development of suitable biomimetic catalytic systems capable of mimicking the promiscuous catalytic properties of such enzymes r...

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Detalhes bibliográficos
Autor principal: Neves,Ademir (author)
Outros Autores: Bortoluzzi,Adailton J. (author), Jovito,Rafael (author), Peralta,Rosely A. (author), Souza,Bernardo de (author), Szpoganicz,Bruno (author), Joussef,Antônio C. (author), Terenzi,Hernán (author), Severino,Patricia C. (author), Fischer,Franciele L. (author), Schenk,Gerhard (author), Riley,Mark J. (author), Smith,Sarah J. (author), Gahan,Lawrence R. (author)
Formato: article
Idioma:eng
Publicado em: 2010
Assuntos:
mixed-valence FeIII FeII complex
unsymmetrical ligand
catalytic promiscuity
diester and DNA cleavage
catecholase activity
Texto completo:http://old.scielo.br/scielo.php?script=sci_arttext&pid=S0103-50532010000700007
País:Brasil
Oai:oai:scielo:S0103-50532010000700007

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http://old.scielo.br/scielo.php?script=sci_arttext&pid=S0103-50532010000700007

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