Optical, magnetic and dielectric properties of non-liquid crystalline elastomers doped with magnetic colloids

Magnetic nanoparticles from magnetic colloidal suspensions were incorporated in the urethane/urea elastomer (PU/PBDO) by swelling fully crosslinked elastomer samples with a toluene and ferrofluid mixture. It is shown that ferrofluid grains can be efficiently incorporated into the matrix of elastomer...

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Detalhes bibliográficos
Autor principal: Neto, A. M. Figueiredo (author)
Outros Autores: Godinho, M. H. (author), Toth-Katona, T. (author), Palffy-Muhoray, P. (author)
Formato: article
Idioma:eng
Publicado em: 2020
Assuntos:
Texto completo:http://hdl.handle.net/10362/99075
País:Portugal
Oai:oai:run.unl.pt:10362/99075
Descrição
Resumo:Magnetic nanoparticles from magnetic colloidal suspensions were incorporated in the urethane/urea elastomer (PU/PBDO) by swelling fully crosslinked elastomer samples with a toluene and ferrofluid mixture. It is shown that ferrofluid grains can be efficiently incorporated into the matrix of elastomers. The dependence of the birefringence of both the pure and ferrofluid-doped elastomer samples on strain is linear. The ratio of birefringence to strain of the ferrofluid-doped samples is greater than that of the pure elastomer samples, indicating that ferrofluid grains are oriented by the strained polymer network. We propose that this strain-induced orientation is due to the shape anisotropy of the nanoparticles.