Electrochemical intramolecular cyclisation of propargyl bromoethers catalysed by nickel complexes

The electrochemical intramolecular cyclisation of propargyl 2-bromoethers 1-3 in N,N'-dimethylformamide at constant current in a diaphragmless cell has been developed using Ni(II) complexes as electron-transfer mediators. During controlled-current electrolyses of solutions of Ni(II) complexes i...

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Bibliographic Details
Main Author: Duñach, E. (author)
Other Authors: Esteves, Ana Paula (author), Medeiros, Maria José (author), Olivero, S. (author)
Format: article
Language:eng
Published: 2005
Subjects:
Electron transfer
Cyclisation
Nickel
Radicals
Heterocycle
Science & Technology
Online Access:http://hdl.handle.net/1822/3063
Country:Portugal
Oai:oai:repositorium.sdum.uminho.pt:1822/3063

Internet

http://hdl.handle.net/1822/3063

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