Analysis of temperature and aging effects on biomedical ultra-high molecular weight polyethylene's grades using a viscoelastic model

The applicability of a proposed viscoelastic model, previously developed to model dynamic behaviour of ultra-high molecular weight polyethylenes (UHMWPE), was assessed using three different UHMWPE medical grades. The dynamic data, collected from literature, was obtained via DMTA (Dynamic Mechanical...

Full description

Bibliographic Details
Main Author: Rui Miranda Guedes (author)
Format: article
Language:eng
Published: 2011
Subjects:
Online Access:https://repositorio-aberto.up.pt/handle/10216/97378
Country:Portugal
Oai:oai:repositorio-aberto.up.pt:10216/97378
Description
Summary:The applicability of a proposed viscoelastic model, previously developed to model dynamic behaviour of ultra-high molecular weight polyethylenes (UHMWPE), was assessed using three different UHMWPE medical grades. The dynamic data, collected from literature, was obtained via DMTA (Dynamic Mechanical Thermal Analysis) operated over a wide temperature and frequency range. The time-temperature superposition principle (TTSP) was applied to dynamic data via the proposed viscoelastic model. A reference temperature of 37 degrees C was selected. It was verified that both horizontal and vertical shifts are necessary to superimpose the dynamic modulus/frequency curves of all UHMWPE grades. Moreover, it was shown that the aging effect can be modelled using an aging-time superposition principle based on the proposed viscoelastic model. Again, both horizontal and vertical shifts were necessary to superimpose the aged and non-aged dynamic modulus/frequency curves at 37 degrees C.