Investigation of a dichlorodioxomolybdenum(VI)-pyrazolylpyridine complex and a hybrid derivative as catalysts in olefin epoxidation

Treatment of the solvent adduct [MoO2Cl2(THF)(2)] with the ligand 2-(1-pentyl-3-pyrazolyl)pyridine (1, abbreviated as pent-pp) gave the dioxomolybdenum(VI) complex [MoO2Cl2(pent-pp)] (2), which was characterised by elemental analysis, H-1 NMR, FT-IR spectroscopy and single crystal X-ray diffraction...

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Bibliographic Details
Main Author: Amarante, Tatiana R. (author)
Other Authors: Neves, Patricia (author), Almeida Paz, Filipe A. (author), Valente, Anabela A. (author), Pillinger, Martyn (author), Goncalves, Isabel S. (author)
Format: article
Language:eng
Published: 1000
Subjects:
CAMBRIDGE STRUCTURAL DATABASE
BOND-VALENCE PARAMETERS
CRYSTAL-STRUCTURE
DIOXOMOLYBDENUM(VI) COMPLEXES
CYCLOOCTENE EPOXIDATION
MOLYBDENUM(VI) COMPLEX
HYDROTHERMAL SYNTHESIS
EFFICIENT CATALYSTS
ORGANIC-SYNTHESIS
DIOXO COMPLEXES
Online Access:http://hdl.handle.net/10773/20066
Country:Portugal
Oai:oai:ria.ua.pt:10773/20066

Internet

http://hdl.handle.net/10773/20066

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