Understanding chemical reactions of CO2 and its isoelectronic molecules with 1-butyl-3-methylimidazolium acetate by changing the nature of the cation: The case of CS2 in 1-butyl-1-methylpyrrolidinium acetate studied by NMR spectroscopy and density functional theory calculations

NMR spectroscopy (H-1, C-13, N-15) shows that carbon disulfide reacts spontaneously with 1-butyl-1-methylpyrrolidinium acetate ([BmPyrro][Ac]) in the liquid phase. It is found that the acetate anions play an important role in conditioning chemical reactions with CS2 leading, via coupled complex reac...

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Bibliographic Details
Main Author: Isabel Cabaco, M. (author)
Other Authors: Besnard, Marcel (author), Chavez, Fabian Vaca (author), Pinaud, Noel (author), Sebastiao, Pedro J. (author), Coutinho, Joao A. P. (author), Danten, Yann (author)
Format: article
Language:eng
Published: 2017
Subjects:
IONIC LIQUIDS
CARBON-DIOXIDE
TRANSITION-STATES
METAL-COMPLEXES
CARBENE
DITHIOCARBOXYLATES
ABSORPTION
GEOMETRIES
SOLVATION
CAPTURE
Online Access:http://hdl.handle.net/10773/19783
Country:Portugal
Oai:oai:ria.ua.pt:10773/19783

Internet

http://hdl.handle.net/10773/19783

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