Cobalt complexes bearing scorpionate ligands: Synthesis, characterization, cytotoxicity and DNA cleavage

A number of novel, water-stable redox-active cobalt complexes of the C-functionalized tripodal ligands tris(pyrazolyl)methane XC(pz)(3) (X = HOCH2, CH2OCH2Py or CH2OSO2Me) are reported along with their effects on DNA. The compounds were isolated as air-stable solids and fully characterized by IR and...

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Bibliographic Details
Main Author: Silva, Telma F. S. (author)
Other Authors: Martins, Luisa (author), Guedes da Silva, Maria de Fátima (author), Fernandes, Alexandra R. (author), Silva, Ana (author), Borralho, Pedro M. (author), Santos, Susana (author), Rodrigues, Cecília M. P. (author), Pombeiro, Armando (author)
Format: article
Language:eng
Published: 2015
Subjects:
Single-pot hydrocarboxylation
Organic molecular-crystals
Peroxidative oxidation
Carboxylic-acids
Metal-free
In-vitro
Tris(Pyrazolyl)Methane ligands
Aqueous systems
Mild conditions
Water clusters
Online Access:http://hdl.handle.net/10400.21/5097
Country:Portugal
Oai:oai:repositorio.ipl.pt:10400.21/5097

Internet

http://hdl.handle.net/10400.21/5097

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