C-scorpionate iron(II) complexes as highly selective catalysts for the hydrocarboxylation of cyclohexane

The C-scorpionate iron(II) complexes [FeCl2{kappa(3)-HC(pz)(3)}](1) (pz = pyrazol-1-yl), Li[FeCl2{kappa(3)-SO3C(pz)(3)}] (2) and the new [FeCl2{kappa(3)-HOCH2C(pz)(3)}] (3) act as catalysts for the hydrocarboxylation of cyclohexane (with CO and H2O) to cyclohexanecarboxylic acid in a remarkable yiel...

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Detalhes bibliográficos
Autor principal: Matias, Inês (author)
Outros Autores: Da Costa Ribeiro, Ana Paula (author), Alegria, Elisabete (author), Pombeiro, Armando (author), Martins, Luisa (author)
Formato: article
Idioma:eng
Publicado em: 2019
Assuntos:
Hydrocarboxylation
Iron
Scorpionate
Homogeneous catalysis
Aqueous medium
Cyclohexane
Carboxylic acid
Texto completo:http://hdl.handle.net/10400.21/9923
País:Portugal
Oai:oai:repositorio.ipl.pt:10400.21/9923

Texto Completo

http://hdl.handle.net/10400.21/9923

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