Organic cyclisations of propargyl and allyl bromoesters in microemulsions catalyzed by electrogenerated Nickel(I) tetramethylcyclam

While the reductive intramolecular cyclisation of propargyl and allyl bromoesters catalysed by [Ni(tmc)]+ gives good yields of the desired products using N,N-dimethylformamide as the solvent, the use of this aprotic solvent presents practical, safety and environmental issues. This paper therefore re...

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Bibliographic Details
Main Author: Esteves, Ana Paula (author)
Other Authors: Neves, C. S. S. (author), Medeiros, Maria José (author), Pletcher, Derek (author)
Format: article
Language:eng
Published: 2008
Subjects:
Microemulsions
Cyclic voltammetry
Electrosynthesis
Electrocatalytic reduction
Intramolecular cyclisation
electrocataiytic reduction
Science & Technology
Online Access:http://hdl.handle.net/1822/26872
Country:Portugal
Oai:oai:repositorium.sdum.uminho.pt:1822/26872

Internet

http://hdl.handle.net/1822/26872

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