Trinuclear CuII Structural isomers: coordination, magnetism, electrochemistry and catalytic activity towards the oxidation of alkanes

The reaction of the Schiff base (3,5-di-tert-butyl-2-hydroxybenzylidene)-2-hydroxybenzohydrazide (H3L) with copper(II) nitrate, acetate or metaborate has led to the isomeric complexes [Cu3(L)2(MeOH)4] (1), [Cu3(L)2(MeOH)2]·2MeOH (2) and [Cu3(L)2(MeOH)4] (3), respectively, in which the ligand L exhib...

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Detalhes bibliográficos
Autor principal: Sutradhar, Manas (author)
Outros Autores: Martins, Luisa (author), Guedes Da Silva, M. Fátima C. (author), Mahmudov, Kamran (author), Liu, Cai-Ming (author), Pombeiro, Armando (author)
Formato: article
Idioma:eng
Publicado em: 2018
Assuntos:
N,O ligands
Copper
Magnetic properties
Electrochemistry
Oxidation
Texto completo:http://hdl.handle.net/10400.21/8078
País:Portugal
Oai:oai:repositorio.ipl.pt:10400.21/8078

Texto Completo

http://hdl.handle.net/10400.21/8078

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