Rheological behaviour of cork-polymer composites for injection moulding

The incorporation of cork in synthetic polymers has become an effective approach to develop new sustainable materials. Cork-polypropylene composites (CPC) filled with three different cork granulometries were studied. Rheological analyses were performed to assess the processability of these CPC and a...

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Detalhes bibliográficos
Autor principal: Magalhães da Silva, Sara P. (author)
Outros Autores: Lima, Paulo Silva (author), Oliveira, José Martinho (author)
Formato: article
Idioma:eng
Publicado em: 1000
Assuntos:
Texto completo:http://hdl.handle.net/10773/16290
País:Portugal
Oai:oai:ria.ua.pt:10773/16290
Descrição
Resumo:The incorporation of cork in synthetic polymers has become an effective approach to develop new sustainable materials. Cork-polypropylene composites (CPC) filled with three different cork granulometries were studied. Rheological analyses were performed to assess the processability of these CPC and a set of experiments was conducted keeping the same matrix/cork weight ratio, varying the cork granulometric distribution. The effect of three different cork granulometries, temperature and the effect of a coupling agent, polypropylene graft maleic anhydride (PPgMA), were analysed. All composites exhibited non-Newtonian, pseudoplastic behaviour. Related to neat PP, cork incorporation led to a viscosity increase. This increase is more significant in the CPC with the lowest powder cork granulometry used. On the other side, the addition of PPgMA resulted on a decrease of CPC viscosity. The experimental results were fitted to Cross-WLF Model through a viscosity master curve obtained by the time etemperature superposition principle (TTSP). This study showed that cork can be considered on the development of sustainable materials for injection moulding technology.