Oxidation of benzyl alcohol by pyridinium dichromate in acetonitrile. Using the para/meta ratio of substituent effects for mechanism elucidation
Rate constants were measured for the oxidation reaction of benzyl alcohol and twenty-five ortho-, meta- and para-monosubstituted derivatives in the temperature range 293-323 K at intervals of 10 K. The kinetics were followed spectrophotometrically in dry acetonitrile acidified with trichloroacetic a...
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| Other Authors: | , , , |
| Format: | article |
| Language: | eng |
| Published: |
2015
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| Subjects: | |
| Online Access: | http://hdl.handle.net/10451/20875 |
| Country: | Portugal |
| Oai: | oai:repositorio.ul.pt:10451/20875 |