Double-Proton-Transfer Processes in Dithiooxamide:  UV-Induced Dithione → Dithiol Reaction and Ground-State Dithiol → Dithione Tunneling

Dithiooxamide [rubeanic acid, NH2C(S)C(S)NH2)] monomers were studied by FTIR spectroscopy combined with the low-temperature matrix-isolation technique. The most stable dithione−diamino tautomer of the compound was exclusively observed in argon matrixes immediately after deposition. Upon UV (λ > 3...

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Bibliographic Details
Main Author: Lapinski, Leszek (author)
Other Authors: Rostkowska, Hanna (author), Khvorostov, Artem (author), Yaman, Müjgan (author), Fausto, Rui (author), Nowak, Maciej J. (author)
Format: article
Language:eng
Published: 2004
Online Access:http://hdl.handle.net/10316/17880
Country:Portugal
Oai:oai:estudogeral.sib.uc.pt:10316/17880

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http://hdl.handle.net/10316/17880

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