Thermal co-evaporation of Sb2Te3 thin-films optimized for thermoelectric applications

Antimony telluride (Sb2Te3) is a chalcogenide material used in thermoelectric applications. The deposition of thin films of Sb2Te3 requires a precisely controlled process to achieve a desirable high thermoelectric figure of-merit. The optimization of the thermal co-evaporation process for p-type Sb2...

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Bibliographic Details
Main Author: Gonçalves, L. M. (author)
Other Authors: Alpuim, P. (author), Rolo, Anabela G. (author), Correia, J. H. (author)
Format: article
Language:eng
Published: 2011
Subjects:
Online Access:http://hdl.handle.net/1822/14345
Country:Portugal
Oai:oai:repositorium.sdum.uminho.pt:1822/14345
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Summary:Antimony telluride (Sb2Te3) is a chalcogenide material used in thermoelectric applications. The deposition of thin films of Sb2Te3 requires a precisely controlled process to achieve a desirable high thermoelectric figure of-merit. The optimization of the thermal co-evaporation process for p-type Sb2Te3 thin-film onto plastic substrates (Kapton© polyimide) for thermoelectric applications is reported. The influence of deposition parameters and composition on thermoelectric properties was studied, seeking optimal thermoelectric performance. Energy-dispersive X-ray spectroscopy, X-ray diffraction, X-ray photoelectron spectroscopy and Raman spectroscopy all confirmed the formation of Sb2Te3 thin films. Seebeck coefficient (up to 190 μVK−1), in-plane electrical resistivity (8–15 μΩm), carrier concentration (1×10^19–7×10^19 cm−3) and Hall mobility (120–180 cm2V−1s−1) were measured at room temperature for the best Sb2Te3 thin-films.