Wastewater treatment of biodiesel production using persulphate ion as an oxidant

The production of biodiesel produces a highly polluting effluent, because presents high values of Chemical Oxygen Demand (COD), oils and fats, among other contaminants. Sodium persulphate is a powerful oxidant (Eº = 2.1V). In addition to the direct oxidation that is favored in alkaline media, it can...

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Bibliographic Details
Main Author: Borralho, Teresa (author)
Format: article
Language:eng
Published: 2020
Subjects:
Online Access:http://hdl.handle.net/20.500.12207/5127
Country:Portugal
Oai:oai:repositorio.ipbeja.pt:20.500.12207/5127
Description
Summary:The production of biodiesel produces a highly polluting effluent, because presents high values of Chemical Oxygen Demand (COD), oils and fats, among other contaminants. Sodium persulphate is a powerful oxidant (Eº = 2.1V). In addition to the direct oxidation that is favored in alkaline media, it can be induced by photolytic processes, catalytic and / or catalytic photos forming sulphate radicals (Eº = 2.6 V) thus providing reaction mechanisms with free radicals like hydroxyl radicals.