A Mn(III) polyoxotungstate in the oxidation of organosulfur compounds by H2O2 at room temperature: an environmentally safe catalytic approach

The tetrabutylammonium (TBA) salt of a Keggin-type polyoxometalate (POM), with the chemical formula TBA(4)H(2)[BW11Mn(H2O)O-39]center dot H2O, TBABW(11)Mn, was evaluated as a catalyst in the oxidation by hydrogen peroxide of several organosulfur compounds, namely benzothiophene (BT), 2-methylbenzoth...

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Bibliographic Details
Main Author: Duarte, Tiago A. G. (author)
Other Authors: Pires, Sonia M. G. (author), Santos, Isabel C. M. S. (author), Simoes, Mario M. Q. (author), Neves, M. Graca P. M. S. (author), Cavaleiro, Ana M. V. (author), Cavaleiro, Jose A. S. (author)
Format: article
Language:eng
Published: 1000
Subjects:
METAL-SUBSTITUTED POLYOXOTUNGSTATES
POLYOXOMETALATE-BASED MATERIALS
HYDROGEN-PEROXIDE
FUEL-OIL
DESULFURIZATION PROCESS
DEEP DESULFURIZATION
PHOSPHOTUNGSTIC ACID
ORGANIC FRAMEWORK
MODEL DIESEL
LIQUID FUELS
Online Access:http://hdl.handle.net/10773/19487
Country:Portugal
Oai:oai:ria.ua.pt:10773/19487

Internet

http://hdl.handle.net/10773/19487

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