A Mn(III) polyoxotungstate in the oxidation of organosulfur compounds by H2O2 at room temperature: an environmentally safe catalytic approach

The tetrabutylammonium (TBA) salt of a Keggin-type polyoxometalate (POM), with the chemical formula TBA(4)H(2)[BW11Mn(H2O)O-39]center dot H2O, TBABW(11)Mn, was evaluated as a catalyst in the oxidation by hydrogen peroxide of several organosulfur compounds, namely benzothiophene (BT), 2-methylbenzoth...

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Detalhes bibliográficos
Autor principal: Duarte, Tiago A. G. (author)
Outros Autores: Pires, Sonia M. G. (author), Santos, Isabel C. M. S. (author), Simoes, Mario M. Q. (author), Neves, M. Graca P. M. S. (author), Cavaleiro, Ana M. V. (author), Cavaleiro, Jose A. S. (author)
Formato: article
Idioma:eng
Publicado em: 1000
Assuntos:
Texto completo:http://hdl.handle.net/10773/19487
País:Portugal
Oai:oai:ria.ua.pt:10773/19487