Coordination Chemistry of the (eta(6)-p-Cymene)ruthenium(II) Fragment with Bis-, Tris-, andTetrakis(pyrazol-1-yl)borate Ligands: Synthesis, Structural, Electrochemical, and CatalyticDiastereoselective Nitroaldol Reaction Studies

Novel [Ru(eta(6)-p-cymene)(kappa(2)-L)X] and [Ru(eta(6)-p-cymene)(kappa(3)-L)]X center dot nH(2)O complexes (L = bis-, tris-, or tetrakis-pyrazolylborate; X = Cl, N-3, PF6, or CF3SO3) are prepared by treatment of [Ru(eta(6)-p-cymene)Cl-2](2) with poly-(pyrazolyl)borate derivatives [M(L)] (L in gener...

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Detalhes bibliográficos
Autor principal: Pettinari, Claudio (author)
Outros Autores: Marchetti, Fabio (author), Cerquetella, Adele (author), Pettinari, Riccardo (author), MONARI, MAGDA (author), Mac Leod, Tatiana C. O. (author), Martins, Luisa (author), Pombeiro, Armando (author)
Formato: article
Idioma:eng
Publicado em: 2013
Assuntos:
Asymmetric Reaction
Ruthenium(II) Arene Complexes
Boron-Pyrazole Chemistry
Human Ovarian-Cancer
PI-Acceptor Ligands
Crystal-Structure
Ferrocene Derivatives
Sulfinato Complexes
Transition-Metals
Anticancer Drugs
Texto completo:http://hdl.handle.net/10400.21/2124
País:Portugal
Oai:oai:repositorio.ipl.pt:10400.21/2124

Texto Completo

http://hdl.handle.net/10400.21/2124

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