In-vitro degradation behaviour of starch/EVOH biomaterials

Blends of corn starch with poly(ethylene-vinyl alcohol) copolymer (SEVA-C) were aged up to 30 days and the degradation solutions were analysed by several techniques. The changes in the mechanical properties as a function of the immersion time can be characterised by an increase in the ductility and...

ver descrição completa

Detalhes bibliográficos
Autor principal: Araújo, M. Alberta (author)
Outros Autores: Vaz, Cláudia M. (author), Cunha, A. M. (author), Mota, M. (author)
Formato: conferenceObject
Idioma:eng
Publicado em: 2000
Assuntos:
Texto completo:http://hdl.handle.net/1822/33704
País:Portugal
Oai:oai:repositorium.sdum.uminho.pt:1822/33704
Descrição
Resumo:Blends of corn starch with poly(ethylene-vinyl alcohol) copolymer (SEVA-C) were aged up to 30 days and the degradation solutions were analysed by several techniques. The changes in the mechanical properties as a function of the immersion time can be characterised by an increase in the ductility and a decrease in the stiffness. Weight loss and water uptake were also evaluated. The morphology and the water absorption capacity of SEVA-C were followed by scanning electron microscopy (SEM) and thermogravimetric analysis (TGA), respectively. The degradation solutions were monitored with anionic chromatography (HPAE-PAD), colorimetric methods and Fourier transformed infra-red spectrophotomety (FT-IR). In the first days of immersion, the released of almost the plasticisers added to the material formulation, mainly glycerol, was the main physical phenomenon. The total polysaccharides increased in solution as a function of immersion time, as a consequence of the chemical degradation. SEVA-C micrographs presented an increase in the surface porosity as a function of immersion time.