Synthesis of PbS nanocrystallites using a novel single molecule precursors approach: X-ray single-crystal structure of Pb(S2CNEtPri)2
The synthesis and characterisation of some lead(II) dithiocarbamato complexes Pb(S2CNRR¾)2 is reported. These compounds were used as single molecule precursors to produce nanocrystalline PbS by their thermolysis in trioctylphosphine oxide. The optical and morphological properties of the resulting Pb...
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| Other Authors: | , , |
| Format: | article |
| Language: | eng |
| Published: |
2012
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| Online Access: | http://hdl.handle.net/10773/5776 |
| Country: | Portugal |
| Oai: | oai:ria.ua.pt:10773/5776 |
| Summary: | The synthesis and characterisation of some lead(II) dithiocarbamato complexes Pb(S2CNRR¾)2 is reported. These compounds were used as single molecule precursors to produce nanocrystalline PbS by their thermolysis in trioctylphosphine oxide. The optical and morphological properties of the resulting PbS nanocrystallites were investigated; the influence of experimental parameters, such as precursor, growth time and temperature, on the final nanodispersed materials is also reported. |
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