Tripyridinium cis-tetrachloridodioxidomolybdate(VI) chloride

In the title compound, (C(5)H(6)N)(3)[MoCl(4)O(2)]Cl, the pyridinium cations are N-H center dot center dot center dot Cl hydrogen bonded to the anionic [MoCl(4)O(2)](2-) complexes and to the two crystallographically independent chloride anions (located on C2 axes). The Mo(6+) centre adopts a highly...

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Bibliographic Details
Main Author: Fernandes, José A. (author)
Other Authors: Gomes, Ana C. (author), Figueiredo, Sonia (author), Gago, Sandra (author), Ribeiro-Claro, Paulo J. A. (author), Gonçalves, Isabel S. (author), Almeida Paz, Filipe A. (author)
Format: article
Language:eng
Published: 2018
Subjects:
Olefin epoxidation
Online Access:http://hdl.handle.net/10400.1/11474
Country:Portugal
Oai:oai:sapientia.ualg.pt:10400.1/11474
Description
Summary:In the title compound, (C(5)H(6)N)(3)[MoCl(4)O(2)]Cl, the pyridinium cations are N-H center dot center dot center dot Cl hydrogen bonded to the anionic [MoCl(4)O(2)](2-) complexes and to the two crystallographically independent chloride anions (located on C2 axes). The Mo(6+) centre adopts a highly distorted octahedral geometry, being surrounded by four chloride and two terminal oxide groups. The oxide ligands are mutually cis.

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