Physicochemical Characterization of New Sulfate Ionic Liquids

In this work, the ionic liquids 1-ethyl-1-methylpyrrolidinium ethylsulfate [EMpyr][ESO4], 1-n-butyl-1- ethylpyrrolidinium ethylsulfate [BEpyr][ESO4], 1-n-butyl-1-methylpyrrolidium methylsulfate [BMpyr][MSO4], and triethylmethylammonium methylsulfate [E3MN][MSO4] were synthesized, and their experimen...

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Bibliographic Details
Main Author: Elena Gómez (author)
Other Authors: Begoña González (author), Miguel Vilas (author), Ángeles Domíngez (author), Emilia Tojo (author)
Format: article
Language:eng
Published: 2011
Subjects:
Online Access:https://hdl.handle.net/10216/104934
Country:Portugal
Oai:oai:repositorio-aberto.up.pt:10216/104934
Description
Summary:In this work, the ionic liquids 1-ethyl-1-methylpyrrolidinium ethylsulfate [EMpyr][ESO4], 1-n-butyl-1- ethylpyrrolidinium ethylsulfate [BEpyr][ESO4], 1-n-butyl-1-methylpyrrolidium methylsulfate [BMpyr][MSO4], and triethylmethylammonium methylsulfate [E3MN][MSO4] were synthesized, and their experimental densities, speeds of sound, dynamic viscosities, and refractive indices were studied as a function of temperature at atmospheric pressure. Thermal expansion coefficient, molar volume, and molar refraction of these ionic liquids were calculated from the experimental density and refractive index values. A thermal analysis for pyrrolidinium and ammonium-based ionic liquids at temperatures between T ) (253.15 and 363.15) K is presented.