Synthesis and catalytic properties of manganese(II) and oxovanadium(IV) complexes anchored to mesoporous MCM-41

Reaction of [MnIII(acac)3] and [VIVO(acac)2] with the 1,4-diazabutadiene (DAB) ligands Ph-DAB-(CH2)3R [R = Si(OEt)3(1a); H (1b)] (L) leads to complexes of the type [MnII(acac)2L] and [VIVO(acac)L]Cl in good yields. These complexes were characterised by spectroscopic techniques, and magnetic measurem...

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Detalhes bibliográficos
Autor principal: Fernandes, Tiago A. (author)
Outros Autores: Nunes, Carla D. (author), Vaz, Pedro D. (author), Calhorda, Maria José (author), Brandão, Paula (author), Rocha, João (author), Gonçalves, Isabel S. (author), Valente, Anabela A. (author), Ferreira, Liliana P. (author), Godinho, Margarida (author), Ferreira, Paula (author)
Formato: article
Idioma:eng
Publicado em: 2008
Assuntos:
Mesoporous materials
Manganese
Oxovanadium
Nitrogen ligands
Epoxidation
Texto completo:http://hdl.handle.net/10316/4331
País:Portugal
Oai:oai:estudogeral.sib.uc.pt:10316/4331

Texto Completo

http://hdl.handle.net/10316/4331

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