Six new 3d-4f heterometallic coordination polymers constructed from pyrazole-bridged Cu(II)Ln(III) dinuclear units

Reactions of lanthanide chlorides, copper hydroxycarbonate and 3,5-pyrazole dicarboxylic acid (H(3)pdc) under hydrothermal conditions result in six new 3d-4f heterometallic coordination polymers with two types of structures. Compounds [CuLn(2)(pdc)(2)(Hpdc)(H2O)(4)]center dot 2H(2)O (Ln = Tb (1), Dy...

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Bibliographic Details
Main Author: Yang, Ting-Hai (author)
Other Authors: Silva, Ana Rosa (author), Shi, Fa-Nian (author)
Format: article
Language:eng
Published: 1000
Subjects:
METAL-ORGANIC FRAMEWORKS
SINGLE-MOLECULE MAGNET
INORGANIC SUBNETWORK
COMPLEXES
LIGAND
CLUSTERS
LN
RELAXATION
CATALYSIS
SULFATE
Online Access:http://hdl.handle.net/10773/19289
Country:Portugal
Oai:oai:ria.ua.pt:10773/19289

Internet

http://hdl.handle.net/10773/19289

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