Hexanuclear and undecanuclear iron(III) carboxylates as catalyst precursors for cyclohexane oxidation

Two multinuclear complexes [Fe-6(mu(3)-O)(2)(mu(4)-O-2)L-10(OAc)(2)(H2O)(2)]center dot 2.625Et(2)O center dot 2.375H(2)O (1) and [(Fe11Cl)-Cl-III-(mu(4)-O)(3)(mu(3)-O)(5)L-16(dmf)(2.5)(H2O)(0.5)]center dot Et2O center dot 1.25dmf center dot 3.8H(2)O (2), where HL = 3,4,5-trimethoxybenzoic acid and d...

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Bibliographic Details
Main Author: Milunovic, Miljan N. M. (author)
Other Authors: Martins, Luisa (author), Alegria, Elisabete (author), Pombeiro, Armando (author), Krachler, Regina (author), Trettenhahn, Guenter (author), Turta, Constantin (author), Shova, Sergiu (author), Arion, Vladimir B. (author)
Format: article
Language:eng
Published: 2013
Subjects:
Single-pot hydrocarboxylation
Mild peroxidative oxidation
Nonheme iron catalysts
Copper triethnolamine complexes
Hydrogen-peroxide
C-H
Alkane hydroxylation
Highly efficient
Metal-free
Online Access:http://hdl.handle.net/10400.21/2887
Country:Portugal
Oai:oai:repositorio.ipl.pt:10400.21/2887

Internet

http://hdl.handle.net/10400.21/2887

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