Cyclohexane oxidation with dioxygen catalyzed by supported pyrazole rhenium complexes

The pyrazole complexes [ReCl2{N2C(O)Ph}(Hpz)(PPh3)2] 2 (Hpz = pyrazole), [ReCl2{N2C(O)Ph}(Hpz)2(PPh3)] 3 and [ReClF{N2C(O)Ph}(Hpz)2(PPh3)] 4, and their precursor [ReOCl3(PPh3)2] 1, immobilized on 3-aminopropyl functionalized silica, catalyze the cyclohexane oxidation with dioxygen, to cyclohexanol a...

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Bibliographic Details
Main Author: Mishra, Gopal S. (author)
Other Authors: Alegria, Elisabete (author), Martins, Luisa (author), Fraústo Da Silva, João (author), Pombeiro, Armando (author)
Format: article
Language:eng
Published: 2020
Subjects:
Rhenium
Cyclohexane
Dioxygen
Carboxylic acids
Radical mechanism
Cyclohexanol
Cyclohexanone
Online Access:http://hdl.handle.net/10400.21/12072
Country:Portugal
Oai:oai:repositorio.ipl.pt:10400.21/12072

Internet

http://hdl.handle.net/10400.21/12072

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