Kinetically unstable 2–isocyanophenol isolated in cryogenic matrices: Vibrational excitation, conformational changes and spontaneous tunneling

Monomers of 2-isocyanophenol were generated in low-temperature solid Ar and N2 matrices by UV-irradiation of benzoxazole and characterized by infrared (IR) spectroscopy. Near–IR narrowband excitation of the first OH-stretching overtone of 2–isocyanophenol isolated in an N2 matrix converted the most...

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Bibliographic Details
Main Author: Jesus, A. J. Lopes (author)
Other Authors: Reva, Igor (author), Nunes, Cláudio M. (author), Roque, José P. L. (author), Pinto, Sandra M. V. (author), Lourenço, Rui Fausto (author)
Format: article
Language:eng
Published: 2020
Subjects:
Matrix-isolation IR-spectroscopy
Conformational changes
Infrared-induced chemistry
Isomerization rate constant
Hydrogen atom tunneling
Online Access:http://hdl.handle.net/10316/91155
Country:Portugal
Oai:oai:estudogeral.sib.uc.pt:10316/91155

Internet

http://hdl.handle.net/10316/91155

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