Monovacant polyoxometalates incorporated into MIL-101(Cr): novel heterogeneous catalysts for liquid phase oxidation

Two novel hybrid composite materials, PW11@MIL-101 and SiW11@MIL-101, were prepared by the inclusion of the potassium salts of the monovacant polyoxotungstates, [PM11O39](7-) (PW11) and [SiW11O39](8-), into the porous Metal-Organic Framework MIL-101(Cr). Materials were characterized by a myriad of s...

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Bibliographic Details
Main Author: Granadeiro, Carlos M. (author)
Other Authors: Barbosa, Andre D. S. (author), Silva, Patricia (author), Almeida Paz, Filipe A. (author), Saini, Vipin K. (author), Fires, Joao (author), de Castro, Baltazar (author), Balula, Salete S. (author), Cunha-Silva, Luis (author)
Format: article
Language:eng
Published: 1000
Subjects:
METAL-ORGANIC FRAMEWORKS
KEGGIN-TYPE POLYOXOTUNGSTATES
MIXED-OXIDE CATALYSTS
HYDROGEN-PEROXIDE
OLEFIN EPOXIDATION
SUBSTITUTED POLYOXOTUNGSTATES
PHOSPHOTUNGSTIC ACID
PORPHYRIN COMPLEXES
BIPHASE MEDIUM
HYBRID SILICA
Online Access:http://hdl.handle.net/10773/20680
Country:Portugal
Oai:oai:ria.ua.pt:10773/20680

Internet

http://hdl.handle.net/10773/20680

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