Selective conformational control by excitation of NH imino vibrational antennas
An imino group was used for the first time as a vibrational antenna to manipulate molecular conformations. Imino-thiol isomers of thioacetamide were generated upon UV-irradiation of its amino-thione tautomer isolated in argon matrices at 11 K. Selective and reversible conformational isomerizations w...
| Main Author: | |
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| Other Authors: | , , , , |
| Format: | article |
| Language: | eng |
| Published: |
2019
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| Online Access: | http://hdl.handle.net/10316/101241 |
| Country: | Portugal |
| Oai: | oai:estudogeral.sib.uc.pt:10316/101241 |