Photoluminescent Thermometer Based on a Phase-Transition Lanthanide Silicate with Unusual Structural Disorder

The hydrothermal synthesis of the novel Na[LnSiO(4)] (Ln = Gd, Eu, Tb) disordered orthorhombic system is reported. At 100 K, and above, these materials are best described in the centrosymmetric orthorhombic Pnma space group. At lower temperatures (structure solved at 30 K) the unit cell changes to b...

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Bibliographic Details
Main Author: Ananias, Duarte (author)
Other Authors: Almeida Paz, Filipe A. (author), Yufit, Dmitry S. (author), Carlos, Luis D. (author), Rocha, Joao (author)
Format: article
Language:eng
Published: 1000
Subjects:
Online Access:http://hdl.handle.net/10773/19319
Country:Portugal
Oai:oai:ria.ua.pt:10773/19319