Rotational Isomerism in Acetic Acid: The First Experimental Observation of the High-Energy Conformer

The high-energy conformer of acetic acid (cis-AA) is produced in an Ar matrix by vibrational excitation of the OH stretching overtone of the ground conformational state (trans-AA). IR-absorption spectroscopy provides a clear identification of the reaction product. cis-AA converts back to trans-AA in...

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Bibliographic Details
Main Author: Maçôas, Ermelinda M. S. (author)
Other Authors: Khriachtchev, Leonid (author), Pettersson, Mika (author), Fausto, Rui (author), Räsänen, Markku (author)
Format: article
Language:eng
Published: 2003
Online Access:http://hdl.handle.net/10316/10620
Country:Portugal
Oai:oai:estudogeral.sib.uc.pt:10316/10620

Internet

http://hdl.handle.net/10316/10620

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