Functionalized BODIPY derivatives as potential fluorescent labels

BODIPY derivatives 1 and 2 were obtained with 16 % and 33 % yield by a two-step reaction: condensation of a pyrrole with the corresponding aldehyde followed by oxidation with DDQ in the presence of BF3OEt2. The two compounds were characterized by the usual spectroscopic techniques and a detailed pho...

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Detalhes bibliográficos
Autor principal: Gonçalves, R. C. R (author)
Outros Autores: Nogueira, M. B. (author), Costa, Susana P. G. (author), Raposo, M. Manuela M. (author)
Formato: conferencePaper
Idioma:eng
Publicado em: 2018
Assuntos:
Texto completo:http://hdl.handle.net/1822/57139
País:Portugal
Oai:oai:repositorium.sdum.uminho.pt:1822/57139
Descrição
Resumo:BODIPY derivatives 1 and 2 were obtained with 16 % and 33 % yield by a two-step reaction: condensation of a pyrrole with the corresponding aldehyde followed by oxidation with DDQ in the presence of BF3OEt2. The two compounds were characterized by the usual spectroscopic techniques and a detailed photophysical study was undertaken. The compounds exhibited intense absorption bands at 502 nm and 497 nm, respectively. Emission studies of the compounds 1 and 2 showed emission bands with maximum wavelength at 518 nm and 519 nm, respectively.