A silicododecamolybdate/pyridinium-tetrazole hybrid molecular salt as a catalyst for the epoxidation of bio-derived olefins

The hybrid polyoxometalate (POM) salt (Hptz)(4)[SiMo12O40].nH(2)O (1) (ptz = 5-(2-pyridyl)tetrazole) has been prepared, characterized by X-ray crystallography, and examined as a catalyst for the epoxidation of cis-cyclooctene (Cy) and bio-derived olefins, namely dl-limonene (Lim; a naturally occurri...

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Bibliographic Details
Main Author: Nunes, Martinique S. (author)
Other Authors: Neves, Patricia (author), Gomes, Ana C. (author), Cunha-Silva, Luis (author), Lopes, Andre D. (author), Valente, Anabela A. (author), Pillinger, Martyn (author), Goncalves, Isabel S. (author)
Format: article
Language:eng
Published: 2021
Subjects:
Polyoxometalate
Inorganic-organic hybrid
Pyridinium
Hydrogen bonds
Epoxidation
Bio-olefins
Chemistry
Online Access:http://hdl.handle.net/10400.1/17041
Country:Portugal
Oai:oai:sapientia.ualg.pt:10400.1/17041

Internet

http://hdl.handle.net/10400.1/17041

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