Chlorination of N-phenylbenzenesulfonamides with NCP in aqueous acetic acid. Using the para/meta ratio of substituent effects for mechanism elucidation
Rate constants were measured for the oxidative chlorination reaction of N-phenylbenzenesulfonamide 2 and twelve ortho-, nine meta- and twelve para-substituted derivatives in the aniline moiety, using 1-chloro-3-methyl-2,6-diphenylpiperidin-4-one ( 1) as chlorinating agent. The kinetics was run in 50...
| Autor principal: | |
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| Outros Autores: | , , , |
| Formato: | article |
| Idioma: | eng |
| Publicado em: |
2015
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| Assuntos: | |
| Texto completo: | http://hdl.handle.net/10451/20878 |
| País: | Portugal |
| Oai: | oai:repositorio.ul.pt:10451/20878 |