Compromise between conjugation length and charge-transfer in nonlinear optical η5-monocyclopentadienyliron(II) complexes with substituted oligo-thiophene nitrile ligands: synthesis, electrochemical studies and first hyperpolarizabilities

A systematic series of η5-monocyclopentadienyliron(II) complexes with substituted oligo-thiophene nitrile ligands of general formula [FeCp(P_P)(NC{SC4H2}nNO2)][PF6] (P_P=dppe, (+)-diop; n=1-3) has been synthesized and characterized. The electrochemical behaviour of the new compounds was explored by...

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Bibliographic Details
Main Author: Mendes, Paulo J. (author)
Format: article
Language:eng
Published: 2012
Subjects:
Iron complexes
Thiophene nitrile ligands
Cyclic voltammetry
Nonlinear optics
Quadratic hyperpolarizabilities
Molecular first hyperpolarizabilities
Online Access:http://hdl.handle.net/10174/5328
Country:Portugal
Oai:oai:dspace.uevora.pt:10174/5328

Internet

http://hdl.handle.net/10174/5328

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