Intermolecular alkyl radical addition to methyl 2-(2,6-Dichlorophenyl)-2H-azirine-3-carboxylate

The 2H-azirine 1 acts as an effective radical acceptor for secondary and tertiary alkyl iodides mediated by triethylborane. The addition proceeds with high regio- and diastereo-selectivity.

Bibliographic Details
Main Author: Lemos, A. (author)
Other Authors: Guimaraes, Emanuel (author), Fortes, Gil (author), Alves, Maria José Chão (author)
Format: article
Language:eng
Published: 2012
Subjects:
Azirinas
Heterocycles
Intermolecular radical addition
Triethylborane
Alfa-aminoesters
Online Access:http://hdl.handle.net/10400.1/1023
Country:Portugal
Oai:oai:sapientia.ualg.pt:10400.1/1023

Internet

http://hdl.handle.net/10400.1/1023

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