Preparation of hybrid organic-inorganic materials based on a di-ureasil matrix doped with lithium bis(trifluoromethanesulfonyl)imide
In this presentation we describe the preparation of solvent-free solid polymer electrolytes (SPEs) by the sol-gel route with the incorporation of controlled quantities of lithium bis(trifluoromethanesulfonyl) imide (LiTFSI) into the host matrix. The host framework of these xerogels, designated as di...
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| Outros Autores: | , , |
| Formato: | article |
| Idioma: | eng |
| Publicado em: |
2008
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| Assuntos: | |
| Texto completo: | http://hdl.handle.net/1822/8674 |
| País: | Portugal |
| Oai: | oai:repositorium.sdum.uminho.pt:1822/8674 |
| Resumo: | In this presentation we describe the preparation of solvent-free solid polymer electrolytes (SPEs) by the sol-gel route with the incorporation of controlled quantities of lithium bis(trifluoromethanesulfonyl) imide (LiTFSI) into the host matrix. The host framework of these xerogels, designated as di-ureasils and represented by d-U(900), contains oxyethylene oligomers with about 15 repeat units bonded at each end to a siliceous backbone through urea bridging links. Electrolytes were characterized by ionic conductivity measurements, cyclic voltammetry at a gold microelectrode and thermal analysis. The results obtained reveal that these hybrid materials are completely amorphous and exhibit appropriate electrochemical characteristics for a variety of applications. |
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