Cyclization of Diazoacetamides Catalyzed by N-Heterocyclic Carbene Dirhodium(II) Complexes
The axial coordination of N-heterocyclic carbene ligands onto dirhodium(II) complexes was examined, together with its role in the intramolecular C-H insertion reactions of alpha-diazoacetamides. The formation of a decarbonylated product occurs by a free-carbene mechanism in which the structures of t...
| Autor principal: | |
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| Outros Autores: | , , , , |
| Formato: | article |
| Idioma: | eng |
| Publicado em: |
2015
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| Assuntos: | |
| Texto completo: | http://hdl.handle.net/10451/21499 |
| País: | Portugal |
| Oai: | oai:repositorio.ul.pt:10451/21499 |