Determination of organochlorine pesticides in agricultural soils applyng Quechers, C-ECD and GC-MS/MS

The organochlorine pesticides (OCPs), due the wide use in agriculture until about 30 years (except the most recent bans by the EU for lindane, methoxychlor and endosulfan) and their chemical stability and slow biodegradation became ubiquitous pollutants. Most OCPs are persistent organic pollutants t...

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Detalhes bibliográficos
Autor principal: Sá,Luísa Correia (author)
Outros Autores: Fernandes,Virgínia Cruz (author), Calhau,Conceição (author), Domingues,Valentina Fernandes (author), Matos,Cristina Delerue (author)
Formato: other
Idioma:eng
Publicado em: 2012
Assuntos:
Texto completo:http://scielo.pt/scielo.php?script=sci_arttext&pid=S0871-018X2012000200037
País:Portugal
Oai:oai:scielo:S0871-018X2012000200037
Descrição
Resumo:The organochlorine pesticides (OCPs), due the wide use in agriculture until about 30 years (except the most recent bans by the EU for lindane, methoxychlor and endosulfan) and their chemical stability and slow biodegradation became ubiquitous pollutants. Most OCPs are persistent organic pollutants that have long life cycles in the environment and being transported for long distances. The residues of pesticides in soil can be absorbed by plants, entering the food chain, leading to bioaccumulation. The objective of this study was to determine the presence of 14 OCPs (HCH (α, β, ζ), HCB, lindane, aldrin, α-endosulfan, dieldrin, p, p'-DDE, endrin, endosulfan β-p-p' -DDD, o-p'-DDT and methoxychlor) in soils of 5 Portuguese regions. The extraction was performed with QuEChERS, analysis by GC-ECD and confirmation by GC-MS/MS. One sample showed a residue above the LOQ, revealing contamination by dieldrin at a concentration of 45.36 µg .kg-1.