Cobalt complexes with pyrazole ligands as catalyst precursors for the peroxidative oxidation of cyclohexane: Z-ray absorption spectroscopy studies and biological applications

[CoCl(-Cl)(Hpz(Ph))(3)](2) (1) and [CoCl2(Hpz(Ph))(4)] (2) were obtained by reaction of CoCl2 with HC(pz(Ph))(3) and Hpz(Ph), respectively (Hpz(Ph)=3-phenylpyrazole). The compounds were isolated as air-stable solids and fully characterized by IR and far-IR spectroscopy, MS(ESI+/-), elemental analysi...

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Bibliographic Details
Main Author: Silva, Telma F. S. (author)
Other Authors: Martins, Luisa (author), Guedes Da Silva, M. Fátima C. (author), Kuznetsov, Maxim L. (author), Fernandes, Alexandra R. (author), Silva, Ana (author), Pan, Chun-Jern (author), Lee, Jyh-Fu (author), Hwang, Bing Joe (author), Pombeiro, Armando (author)
Format: article
Language:eng
Published: 2015
Subjects:
Cobalt
Cyclic voltammetry
Cyclohexane oxidation
Invitro cytotoxicity
Pyrazole based ligands
X-ray absorption spectroscopy
Online Access:http://hdl.handle.net/10400.21/4927
Country:Portugal
Oai:oai:repositorio.ipl.pt:10400.21/4927

Internet

http://hdl.handle.net/10400.21/4927

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