Synthesis and Coordination Chemistry of a New N-4-Polydentate Class of Pyridyl-Functionalized Scorpionate Ligands: Complexes of Fe-II, Zn-II, V-IV, Pd-II and Use for Heterobimetallic Systems

The new potentially N-4-multidentate pyridyl-functionalized scorpionates 4-((tris-2,2,2-(pyrazol-1-ypethoxy)methyl)pyridine (TpmPy, (1)) and 4-((tris-2,2,2-(3-phenylpyrazol-1-yl)ethoxy)methyl)pyridine (TpmPy(Ph), (2)) have been synthesized and their coordination behavior toward Fe-II, Ni-II, Zn-II,...

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Bibliographic Details
Main Author: Wanke, Riccardo (author)
Other Authors: Guedes Da Silva, M. Fátima C. (author), Lancianesi, Stefano (author), Silva, Telma F. S. (author), Martins, Luisa (author), Pettinari, Claudio (author), Pombeiro, Armando (author)
Format: article
Language:eng
Published: 2011
Subjects:
Spin-state crossover
Tris(Pyrazolyl) methane ligands
Peroxidative oxidation
Molecular materials
Infrared spectra
Angular-overlap
Iron(II)
Palladium(II)
Units
Zinc
Online Access:http://hdl.handle.net/10400.21/557
Country:Portugal
Oai:oai:repositorio.ipl.pt:10400.21/557

Internet

http://hdl.handle.net/10400.21/557

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