Spectroscopic Study of the Hydration Equilibria and Water Exchange Dynamics of Lanthanide(III) Complexes of 1,7-Bis(carboxymethyl)-1,4,7,10-tetraazacyclododecane (DO2A)

The hydration state of a series of [Ln(DO2A)(H2O)n]+ complexes in aqueous solution at pH = 6.4-7.0 was studied by measuring the lanthanide-induced 17O shifts (LIS) of water [Ln includes elements from Ce to Yb; DO2A = 1,7-bis(carboxymethyl)-1,4,7,10-tetraazacyclododecane]. Their contact contribution,...

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Detalhes bibliográficos
Autor principal: Yerly, Fabrice (author)
Outros Autores: Dunand, Frank A. (author), Tóth, Éva (author), Figueirinha, Artur (author), Kovács, Zoltán (author), Sherry, A. Dean (author), Geraldes, Carlos F. G. C. (author), Merbach, André E. (author)
Formato: article
Idioma:eng
Publicado em: 2000
Texto completo:http://hdl.handle.net/10316/8104
País:Portugal
Oai:oai:estudogeral.sib.uc.pt:10316/8104