Mutual binary solubilities: perfluoromethylcyclohexane-hydrocarbons
Mutual binary solubility data for perfluoromethylcyclohexane+n-hexane, n-heptane, n-octane, n-nonane, 1-hexene and 1-heptene are reported. NRTL and UNIQUAC parameters, for each experimental temperature, were obtained using a NewtonRaphson technique and the parameters so obtained were linearly correl...
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| Formato: | article |
| Idioma: | eng |
| Publicado em: |
1988
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| Texto completo: | http://hdl.handle.net/1822/41780 |
| País: | Portugal |
| Oai: | oai:repositorium.sdum.uminho.pt:1822/41780 |
| Resumo: | Mutual binary solubility data for perfluoromethylcyclohexane+n-hexane, n-heptane, n-octane, n-nonane, 1-hexene and 1-heptene are reported. NRTL and UNIQUAC parameters, for each experimental temperature, were obtained using a NewtonRaphson technique and the parameters so obtained were linearly correlated with T and T1. UNIFAC group parameters for the interaction CH2/CF3 and CH=CH2/CF3 were obtained from mutual solubility data using the same technique. UNIFAC parameters were correlated with the number of carbon atoms and temperature. |
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