Bismuth-catalyzed allylic oxidation using t-butyl hydroperoxide
Bismuth(III) salts are efficient catalysts for the selective allylic oxidation using tert-butyl hydroperoxide. BiCl3 is especially effective and can be easily recovered and reused as BiOCl. Using BiCl3/K-10 as catalyst, an increase in the reaction rate was observed.
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| Formato: | article |
| Idioma: | eng |
| Publicado em: |
2005
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| Texto completo: | http://hdl.handle.net/10316/5755 |
| País: | Portugal |
| Oai: | oai:estudogeral.sib.uc.pt:10316/5755 |