Bismuth-catalyzed allylic oxidation using t-butyl hydroperoxide
Bismuth(III) salts are efficient catalysts for the selective allylic oxidation using tert-butyl hydroperoxide. BiCl3 is especially effective and can be easily recovered and reused as BiOCl. Using BiCl3/K-10 as catalyst, an increase in the reaction rate was observed.
| Main Author: | |
|---|---|
| Other Authors: | |
| Format: | article |
| Language: | eng |
| Published: |
2005
|
| Subjects: | |
| Online Access: | http://hdl.handle.net/10316/5755 |
| Country: | Portugal |
| Oai: | oai:estudogeral.sib.uc.pt:10316/5755 |
| Summary: | Bismuth(III) salts are efficient catalysts for the selective allylic oxidation using tert-butyl hydroperoxide. BiCl3 is especially effective and can be easily recovered and reused as BiOCl. Using BiCl3/K-10 as catalyst, an increase in the reaction rate was observed. |
|---|