Dichlorodioxomolybdenum(VI) complexes bearing oxygen-donor ligands as olefin epoxidation catalysts

Treatment of the solvent adduct [MoO2Cl2(THF)(2)] with either 2 equivalents of N,N-dimethylbenzamide (DMB) or 1 equivalent of N,N'-diethyloxamide (DEO) gave the dioxomolybdenum(VI) complexes [MoO2Cl2(DMB)(2)] (1) and [MoO2Cl2(DEO)] (2). The molecular structures of 1 and 2 were determined by sin...

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Bibliographic Details
Main Author: Oliveira, Tania S. M. (author)
Other Authors: Gomes, Ana C. (author), Lopes, Andre D. (author), Lourenco, Joao P. (author), Almeida Paz, Filipe A. (author), Pillinger, Martyn (author), Goncalves, Isabel S. (author)
Format: article
Language:eng
Published: 1000
Subjects:
PHOSPHINE OXIDE LIGANDS
BIDENTATE LEWIS-BASE
CRYSTAL-STRUCTURES
MOLECULAR-STRUCTURE
ADDITION-COMPOUNDS
MOLYBDENUM(VI) COMPLEXES
DIOXOMOLYBDENUM(VI)-BIPYRIDINE COMPLEXES
SPECTROSCOPIC CHARACTERIZATION
ORGANOMOLYBDENUM(VI)
REACTIVITY
Online Access:http://hdl.handle.net/10773/19781
Country:Portugal
Oai:oai:ria.ua.pt:10773/19781

Internet

http://hdl.handle.net/10773/19781

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