Homo-and heteropolymetallic 3-(2-pyridyl)pyrazolate manganese and rhenium complexes
fac-[MBr(CO)(3)(pypzH)] (M = Mn, Re; pypzH = (3-(2-pyridyl) pyrazole) complexes are prepared from fac[ MBr(CO)(3)(NCMe)(2)] and pypzH. The result of their deprotonation depends on the metallic substrate: the rhenium complex affords cleanly the bimetallic compound [fac-{Re(CO)(3)(mu(2)-pypz)}] 2 (mu(...
Main Author: | |
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Other Authors: | , , , , , , |
Format: | article |
Language: | eng |
Published: |
2015
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Subjects: | |
Online Access: | http://hdl.handle.net/10400.21/4943 |
Country: | Portugal |
Oai: | oai:repositorio.ipl.pt:10400.21/4943 |