Heteroaromatic benzyl ethers as intermediates for palladium-catalysed transfer hydrogenolysis of benzyl alcohols

A chemoselective and easy to carry procedure for the hydrogenolysis of benzyl alcohols is described. Benzyl alcohols are readily converted into tetrazolyl and benzisothiazolyl ethers that can be catalytically hydrogenolysed to toluenes over palladium-on-charcoal using hydrogen donors. The effect of...

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Bibliographic Details
Main Author: Araujo, Nuna C. P. (author)
Other Authors: Brigas, Amadeu (author), Cristiano, Maria Lurdes Santos (author), Frija, L. (author), Guimarães, Emanuel M. O. (author), Loureiro, Rui M. S. (author)
Format: article
Language:eng
Published: 2014
Subjects:
Palladium-on-charcoal
Transfer hydrogenolysis
Tetrazoles
Benzisothiazoles
Online Access:http://hdl.handle.net/10400.1/4259
Country:Portugal
Oai:oai:sapientia.ualg.pt:10400.1/4259

Internet

http://hdl.handle.net/10400.1/4259

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